Potassium (2,2′-bipyridine-κ2 N,N′)bis(carbonato-κ2 O,O′)cobaltate(III) dihydrate
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چکیده
In the title compound, K[Co(CO(3))(2)(C(10)H(8)N(2))]·2H(2)O, the Co(III) atom is coordinated by two bipyridine N atoms and four O atoms from two bidentate chelating carbonate anions, and thus adopts a distorted octa-hedral N(2)O(4) environment. The [Co(bipy)(CO(3))(2)](-) (bipy is 2,2'-bipyridine) -units are stacked along [100] via π-π stacking inter-actions, with inter-planar distances between the bipyridine rings of 3.36 (4) and 3.44 (6) Å, forming chains. Classical O-H⋯O hydrogen-bonding inter-actions link the chains, forming channels along (100) in which the K(+) ions reside and leading to a three-dimensional supra-molecular architecture.
منابع مشابه
Bis(μ-3-nitrophthalato-κ2 O 1:O 2)bis[aqua(2,2′-bipyridine-κ2 N,N′)copper(II)] dihydrate
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